Polymerization of benzyl thiocyanate on silver nanoparticles and the formation of polymer coated nanoparticles
نویسنده
چکیده
Polymerization of benzylthiocyanate on silver nanoparticles produces organic shell covered nanoparticles with controllable thickness in a one-pot process. Gram scale quantities of core–shell materials have been synthesized by this method. The methodology involves the addition of the precursor into Ag–citrate solution and the shell nucleates over a period of three weeks with complete precipitation of the core–shell material which can be dispersed subsequently in organic solvents. The material has been characterized using transmission electron microscopy, X-ray diffraction, FT-IR, laser desorption mass spectrometry, thermogravimetry, surface enhanced resonance Raman spectroscopy (SERRS) and Raman imaging. A typical composite material consists of a silver core of 40 nm diameter coated with a polymeric shell of 8 nm thickness. The polymer exhibits characteristic features in mass spectrometry and vibrational spectroscopy. The core–shell structure of nanoparticles is imaged for the first time using the Raman intensity of the shell. Proton assisted polymerization of benzylthiocyanate occurs on the silver surface, leading to a linear chain which subsequently deposits on the nanoparticle surface resulting in the core–shell structure.
منابع مشابه
Synthesis and characterization of silver nanoparticles and its immobilization on alginate coated sutures for the prevention of surgical wound infections and the in vitro release studies
The Silver nanoparticles are well-known for their antimicrobial, anti-inflammatory wound healing abilities. We synthesized Silver nanoparticles using chemical reduction method and the formation of the silver nanoparticles was characterized by UV-Vis absorption spectroscopy, FT-IR and SEM techniques. The minimum inhibitory concentration of the synthesized nanoparticles was determined for both gr...
متن کاملSynthesis and characterization of silver nanoparticles and its immobilization on alginate coated sutures for the prevention of surgical wound infections and the in vitro release studies
The Silver nanoparticles are well-known for their antimicrobial, anti-inflammatory wound healing abilities. We synthesized Silver nanoparticles using chemical reduction method and the formation of the silver nanoparticles was characterized by UV-Vis absorption spectroscopy, FT-IR and SEM techniques. The minimum inhibitory concentration of the synthesized nanoparticles was determined for both gr...
متن کاملSynthesis and characterization of Polyvinyl Alcohol-Polypyrrole-Silver nanocomposite polymer films
The present paper describes the preparation and characterization of Polyvinyl Alcohol-Polypyrrole-Silver Nanocomposite (PVA-PPy-Ag NC) films. The prepared films were conducting, freestanding, flexible, and robust. Silver nanoparticles (Ag NPs) were synthesized from an aqueous solution of silver nitrate using trisodium citrate as a reductant. The casting solution for the films was prepared by in...
متن کاملSimultaneous templating of polymer nanocapsules and entrapped silver nanoparticles.
Nanorattles made of hollow polymer nanocapsules with entrapped silver nanoparticles were synthesized in one step by using lipid vesicles as templates. Free radical photoinitiator facilitated both polymerization within the bilayer and formation of metal nanoparticles in the aqueous core.
متن کاملحذف بخار جیوه از هوای مطبهای دندانپزشکی با استفاده از یک سامانه پالایش گر مبتنی بر نانوذرات نقره
Background & objective: Mercury is a toxic and bio-accumulative pollutant that has adverse effects on environmental and human health. There have been a number of attempts to regulate mercury emissions tothe atmosphere. Silver nanoparticles are a number of materials that have highly potential to absorb mercury and formation of mercury amalgam.The aim of this study is removal of mercury va...
متن کامل